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Technical Paper

Development of a Desulfurization Strategy for a NOx Adsorber Catalyst System

2001-03-05
2001-01-0510
The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.
Technical Paper

Modeling the Effect of Substrate Cell Shape on Conversion in Monolith Catalysts

2001-03-05
2001-01-0932
Mass transfer limitations from the bulk gas phase to the surface of the catalyst as well as mass transfer limitations within the washcoat itself have important effects on conversion in washcoated monolith catalysts. These factors depend upon the shape of the channel as well as the loading of washcoat material. This paper outlines a method to describe the washcoat distribution profile for different channel shapes and washcoat loadings. This allows for prediction of effectiveness factors and bulk mass transfer coefficients as a function of cell geometry and washcoat loading for the oxidation of propane. It was found that differences in the diffusion limitations within the washcoat control conversion in the catalyst more than differences in bulk mass transfer rates when comparing different cell shapes. The results show that optimum washcoat loadings exist for the geometry of each cell, and that these optimum loadings are a function of catalyst temperature.
Technical Paper

Correlating Stressed Environmental Testing of Structural Composites to Service

2001-03-05
2001-01-0094
A compact in-situ tensile stress fixture was designed for the study of the combined effects of stress and automotive environments on structural glass fiber-reinforced composite materials. With this fixture, a standardized 300 hour laboratory screening test was developed to compare the residual property loss of composite materials due to concurrent exposure to stress and environment. It is of great importance that the data gathered in the laboratory have correlation to on-vehicle (in-service) performance, and that both lab and real world data be taken with a test system (in-situ test fixtures) capable of providing accurate and consistent results under either test condition.
Technical Paper

Gear Whine Improvements for an Automatic Transmission through Design Retargeting and Manufacturing Variability Reduction

2001-04-30
2001-01-1505
Gear whine in 1st gear for an automatic transmission that has been in production for nearly thirty years was identified as an NVH issue. Due to advances in vehicle level refinement, and reduction of other masking noises, the automatic transmission gear whine became an issue with the customer. Since the transmission was already in production, the improvements had to be within the boundaries of manufacturing feasibility with existing equipment to avoid costly and time consuming investment in new machines. The approach used was one of identifying optimum values of existing gear parameters to provide a reduction in passenger compartment noise. The problem was in a light truck application. Objective noise measurements were recorded for 10 transmissions from more than 50 driven in vehicles. The transmissions were disassembled and the gears inspected.
Technical Paper

Analytical and Experimental Techniques in Solving the Plastic Intake Manifold NVH

2001-04-30
2001-01-1544
The intent of this paper is to summarize the work of the V8 power plant intake manifold radiated noise study. In a particular V8 engine application, customer satisfaction feedback provided observations of existing unpleasant noise at the driver's ear. A comprehensive analysis of customer data indicated that a range from 500 to 800 Hz suggests a potential improvement in noise reduction at the driver's ear. In this study the noise source was determined using various accelerometers located throughout the valley of the engine and intake manifold. The overall surface velocity of the engine valley was ranked with respect to the overall surface velocity of the intake manifold. An intensity mapping technique was also used to determine the major component noise contribution. In order to validate the experimental findings, a series of analysis was also conducted. The analysis model included not only the plastic intake manifold, but also the whole powertrain.
Technical Paper

Development and Validation of a Computational Process for Pass-By Noise Simulation

2001-04-30
2001-01-1561
The Indirect Boundary Element Analysis is employed for developing a computational pass-by noise simulation capability. An inverse analysis algorithm is developed in order to generate the definition of the main noise sources in the numerical model. The individual source models are combined for developing a system model for pass-by noise simulation. The developed numerical techniques are validated through comparison between numerical results and test data for component level and system level analyses. Specifically, the source definition capability is validated by comparing the actual and the computationally reconstructed acoustic field for an engine intake manifold. The overall pass-by noise simulation capability is validated by computing the maximum overall sound pressure level for a vehicle under two separate driving conditions.
Technical Paper

Engine Excitation Decomposition Methods and V Engine Results

2001-04-30
2001-01-1595
Engine excitation forces have been studied in the past using one of two methods; a lumped sum or a totally distributed approach. The lumped sum approach gives the well-understood engine inherent unbalance and the totally distributed approach is used in engine CAE models to determine the overall engine response. The approach that will be described in this paper identifies an intermediate level of sophistication. The methodology implemented considers single cylinder forces on the engine block, piston side thrust and main bearing forces, and decomposes them into their order content. The forces are then phased and geometrically distributed appropriately for each cylinder and then each order is analyzed relative to know distributions that are NVH concerns, V-block breathing, block side wall breathing, and block lateral and vertical bending.
Technical Paper

Research and Development of Controlled Auto-Ignition (CAI) Combustion in a 4-Stroke Multi-Cylinder Gasoline Engine

2001-09-24
2001-01-3608
Controlled Auto-Ignition (CAI) combustion has been achieved in a production type 4-stroke multi-cylinder gasoline engine. The engine was based on a Ford 1.7L Zetec-SE 16V engine with a compression ratio of 10.3, using substantially standard components modified only in design dimensions to control the gas exchange process in order to significantly increase the trapped residuals. The engine was also equipped with Variable Cam Timing (VCT) on both the intake and exhaust camshafts. It was found that the largely increased trapped residuals alone were sufficient to achieve CAI in this engine and with VCT, a range of loads between 0.5 and 4 bar BMEP and engine speeds between 1000 and 3500 rpm were mapped for CAI fuel consumption and exhaust emissions. The measured CAI results were compared with those of Spark Ignition (SI) combustion in the same engine but with standard camshafts at the same speeds and loads.
Technical Paper

Products and Intermediates in Plasma-Catalyst Treatment of Simulated Diesel Exhaust

2001-09-24
2001-01-3512
A simulated diesel exhaust is treated with a nonthermal plasma discharge under steady state conditions. The plasma effluent is then passed through a sodium zeolite-Y (NaY) catalyst followed by a platinum oxidation catalyst. Detailed FTIR measurements of gas composition are taken before, between, and after the treatment stages. The plasma discharge causes oxidation of NO primarily to NO2, with methyl nitrate and nitric acid byproducts. At the same time, HC is partially oxidized, creating species such as formaldehyde, acetaldehyde, CO and other partial oxidation products. When this mixture passes over the NaY catalyst, part of the NOx is reduced to N2, with the remainder primarily in the form of NO. Methyl nitrate decomposes to form methanol and NOx, and nitric acid is consumed. There is little HC conversion on this catalyst. Small quantities of HCN and N2O are formed. When the mixture then passes over the platinum catalyst, further NOx conversion occurs.
Technical Paper

Selective Reduction of NOx in Oxygen Rich Environments with Plasma-Assisted Catalysis: The Role of Plasma and Reactive Intermediates

2001-09-24
2001-01-3513
The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.
Technical Paper

Cascade Processing of NOx by Two-Step Discharge/Catalyst Reactors

2001-09-24
2001-01-3509
We present here a phenomenological analysis of a cascade of two-step discharge-catalyst reactors. That is, each step of the cascade consists of a discharge reactor in series with a catalyst bed. These reactors are intended for use in the reduction of tailpipe emission of NOx from diesel engines. The discharge oxidizes NO to NO2, and partially oxidizes HC. The NO2 then reacts on the catalyst bed with hydrocarbons and partially oxidized HCs and is reduced to N2. The cascade may be essential because the best catalysts for this purpose that we have also convert significant fractions of the NO2 back to NO. As we show, reprocessing the gas may not only be necessary, but may also result in energy savings and increased device reliability.
Technical Paper

Fuel Economy Benefit of Cylinder Deactivation - Sensitivity to Vehicle Application and Operating Constraints

2001-09-24
2001-01-3591
A Variable Displacement Engine (VDE) improves fuel economy by deactivating half the cylinders at light load. The actual fuel economy benefit attained in the vehicle depends on how often cylinders can be deactivated, which is a function of test cycle, engine size, and vehicle weight. In practice, cylinder deactivation will also be constrained by NVH (noise, vibration, and harshness). This paper presents fuel economy projections for VDE in several different engine and vehicle applications. Sensitivity to NVH considerations is quantified by calculating fuel economy with and without cylinder deactivation in various operating modes: idle, low engine speed, 1st and 2nd gear, and warm-up after cold start. The effects of lug limits and calibration hysteresis are also presented.
Technical Paper

Laboratory Assessment of the Oxidation and Wear Performance Capabilities of Low Phosphorus Engine Oils

2001-09-24
2001-01-3541
Meeting upcoming stringent emission standards will require that exhaust gas catalyst systems become active very quickly, function at very high efficiencies and maintain those capabilities at high mileages. This means that contamination of the catalysts by engine oil derived poisons must be minimized. Phosphorus compounds, derived from the zinc dialkyldithio-phosphate (ZDTP) additives that provide antiwear and antioxidant activity, are a principal contaminant that can increase catalyst light off times and reduce catalyst efficiency. Therefore, reducing the concentration of, or eliminating, phosphorus in engine oils is desirable. Doing so, however, requires that oils be reformulated to ensure that wear protection will not be compromised and that oxidation stability will be maintained. To address these concerns, laboratory tests for evaluating oil oxidation and wear performance have been developed and used to evaluate developmental low phosphorus oils.
Technical Paper

The New 1.0l Supercharger Zetec RoCam Engine

2002-11-19
2002-01-3438
The current Brazilian tax legislation promotes vehicles, powered by engines with up to 1.0l displacement. In order to offer the customer an engine with the maximum tax advantage, a supercharged derivative of the Ford 1.0l Zetec RoCam engine was developed. The market specific boundary conditions in South America require powertrains with immediate response especially at low engine speeds. This can be achieved by a supercharged engine concept. The paper discusses the required engine modifications for the supercharger application. The combustion system was changed to benefit from the higher volumetric efficiency, including the optimisation of the intake, exhaust and bypass control system. Extensive modifications of the base engine were required to adapt the engine to the higher thermal load and the specific boundary condition of a supercharger application.
Technical Paper

Boosted Gasoline Direct Injection Engines: Comparison of Throttle and VGT Controllers for Homogeneous Charge Operation

2002-03-04
2002-01-0709
In this paper, we compare controllers for the electronic throttle and variable geometry turbocharger in boosted stoichiometric gasoline direct injection engines. The control objectives are fast response and small overshoot of the intake manifold pressure. The problem is treated within the multi-objective optimization framework, applied to a simulation model of the engine. Pareto optimal fronts are constructed for each of the controllers and compared to each other. The best controller is thereby identified and further options to improve its response via preview-based control are discussed.
Technical Paper

On-line Oxygen Storage Capacity Estimation of a Catalyst

2003-03-03
2003-01-1000
Presented in this paper is an on-line method for estimating the oxygen storage capacity contained within a catalyst. The oxygen storage capacity of a catalyst changes over time due to catalyst brick temperatures, poisoned catalyst sites, and thermal aging. Information regarding the current oxygen storage capacity of a catalyst is advantageous in the development of robust emission control strategies and on-board diagnostics. The method of collecting the oxygen storage capacity information is extremely important for measurement accuracy and repeatability. Furthermore, the information must be obtained in such a way that it is transparent to the operator and may be implemented on-line during normal drive cycles. This on-line method for estimation of oxygen storage capacity of a catalyst has been demonstrated on a Ford F150 platform with an underbody catalyst.
Technical Paper

Eliminating Piston Slap through a Design for Robustness CAE Approach

2003-05-05
2003-01-1728
Piston slap is a problem that plagues many engines. One of the most difficult aspects of designing to eliminate piston slap is that slight differences in operating conditions and in part geometries from build to build can create large differences in the magnitude of piston slap. In this paper we will describe a design for robustness CAE approach to eliminating piston slap. This approach considers the variations of the significant control factors in the design, e.g. piston pin offset, piston skirt design, etc. as well as the variation in the noise factors the system is subjected to, e.g. assembly clearance, skirt collapse, peak cylinder pressure, cylinder pressure rise rate, and location of peak cylinder pressure. Using analytical knowledge about how these various factors impact the generation of piston slap, a piston design for low levels of piston slap can be determined that is robust to the various noise factors.
Technical Paper

Effect of Sac Volume on Injector Performance

1992-02-01
920680
The “Sac” is a small volume within the fuel flow path of an electronic fuel injector. In this study, it is defined as the volume between the valve seat (fuel shut off point) and the entrance to the final metering orifice of the injector. This sac causes fuel injectors to deliver uncalibrated excess fuel when the engine is operated under closed throttle, high manifold vacuum conditions such as vehicle decelerations or idle. This paper describes a simple mass balance model used to predict the effect of the sac volume on injector fuel delivery under extreme operating conditions. The model prediction compares directly with experimental results for injectors with different sac volumes.
Technical Paper

Effect of Mileage Accumulation on Particulate Emissions from Vehicles Using Gasoline with Methylcyclopentadienyl Manganese Tricarbonyl

1992-02-01
920731
Particulate and manganese mass emissions have been measured as a function of mileage for four Escort and four Explorer vehicles using 1) MMT (Methylcyclopentadienyl Manganese Tricarbonyl) added to the gasoline at 1/32 g Mn/gal and 2) gasoline without MMT. The MMT was used in half of the fleet starting at 5,000 miles. The vehicles were driven on public roads at an average speed of 54 mph to accumulate mileage. This report describes the particulate and manganese emissions, plus emissions of four air toxics at 5,000, 20,000, 55,000, 85,000 and 105,000 miles. Four non-regulated emissions were measured and their average values for vehicles without MMT were 0.6 mg/mi for formaldehyde, 0.7 mg/mi for 1,3-butadiene, 9 mg/mi for benzene and 12 mg/mi for toluene. Corresponding values for MMT-fueled vehicles were between 1.5 and 2.4 times higher.
Technical Paper

The Relationship Between Catalyst Hydrocarbon Conversion Efficiency and Oxygen Storage Capacity

1992-02-01
920831
Measurements of oxygen storage capacity (OSC) and HC conversion efficiency for 17 catalysts were carried out in the laboratory. All catalysts with steady state HC efficiency below 90% were found to have roughly equivalent and very low capacities to store oxygen. However, catalyst oxygen storage capacity was seen to rise sharply with HC conversion efficiency in excess of 90 percent. These results parallel the trends which are observed between rear HEGO/EGO indexes for OBD-II catalyst monitoring and HC conversion efficiency. In addition, temperature programed reduction (TPR) was found to lend insight into the relationship between catalyst OSC and HC conversion efficiency by providing a qualitative understanding of the mechanisms by which OSC deteriorates. TPR profiles showed that most of the usable oxygen storage is derived from surface ceria which is interacted with precious metals.
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